Adhāra Viveka

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Plastic Pyrolysis

Mass Balance — 100 kg In, What Comes Out

A Sankey mass balance traces every kilogram of incoming plastic through the pre-processing and reactor stages — 100 kg of mixed waste becomes 63 kg of pyrolysis oil, 18 kg of syngas, 7 kg of char, and 2 kg of residue, with 10 kg lost in pre-processing.

Sankey flow diagram starting from 100 kg incoming mixed plastic at the left, splitting into three pre-processing loss streams (5 kg sorting rejects, 3 kg washing sludge loss, 2 kg shredding dust) flowing downward, and 90 kg continuing right into the reactor block, which then splits into four output streams: 63 kg pyrolysis oil flowing right, 18 kg syngas flowing upper right, 7 kg carbon char flowing lower right, and 2 kg residue flowing down, with stream widths proportional to mass flows
Sankey flow diagram starting from 100 kg incoming mixed plastic at the left, splitting into three pre-processing loss streams (5 kg sorting rejects, 3 kg washing sludge loss, 2 kg shredding dust) flowing downward, and 90 kg continuing right into the reactor block, which then splits into four output streams: 63 kg pyrolysis oil flowing right, 18 kg syngas flowing upper right, 7 kg carbon char flowing lower right, and 2 kg residue flowing down, with stream widths proportional to mass flows
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How to read this sketch

This is a Sankey flow diagram where stream width is proportional to mass. Read it left to right:

  • 100 kg feed (left, widest stream): All mass starts here — the total incoming plastic.
  • Pre-processing losses (downward streams): Three narrow streams split off during pre-processing — sorting rejects, wash sludge, and dust. Total ~10 kg.
  • 90 kg into reactor (main stream continues right): The narrowed main flow after pre-processing losses.
  • Reactor block: The mass splits into four output streams of different widths.
  • Oil stream (widest output, 63 kg): The largest output — proportional width shows it is the dominant product.
  • Syngas stream (18 kg): Second largest — recycled as fuel, not a sellable product.
  • Char stream (7 kg): Third — sellable but low value per kg.
  • Residue (2 kg, smallest stream): Losses and unaccounted.

About this sketch

A mass balance is the accountant's tool for a pyrolysis plant — it tells you where every kilogram of feedstock ends up and validates whether the plant is performing as designed. This Sankey diagram traces a typical 100 kg batch of incoming mixed plastic from the gate to the four output streams.

Of the 100 kg arriving at the plant gate, approximately 10 kg is lost or rejected in pre-processing: about 5 kg removed as sorting rejects (metals, non-plastic contaminants, PVC, PET), 3 kg as washing sludge loss (soil and organic contamination removed in the wash tank), and 2 kg as shredder and granulator dust loss. This leaves 90 kg of clean, dry feedstock entering the reactor.

Inside the reactor at 350–550°C, the 90 kg of plastic cracks into four product fractions: 63 kg as pyrolysis oil (70% of reactor input, 63% of total input), which represents the condensed liquid from the condenser train. 18 kg as syngas (non-condensable gas, 20% of reactor input) — most of this loops back to the furnace as fuel. 7 kg as carbon char (approximately 8% of reactor input). 2 kg as residue — uncondensed lights, moisture-driven losses, and minor unaccounted fractions.

These numbers represent a typical clean mixed PE/PP feedstock. The Sankey changes significantly with feedstock composition: highly contaminated mixed waste might lose 20–25 kg in pre-processing and produce only 50–55 kg of oil. Clean industrial PE scrap might lose only 3–5 kg in pre-processing and yield 72–78 kg of oil per 100 kg input. The mass balance is the diagnostic that shows whether the plant and feedstock are performing together as expected.

Key insights

  • For every 100 kg of incoming mixed plastic, approximately 10 kg is lost in pre-processing — improving sorting and washing quality reduces this loss and increases reactor input.
  • Oil at 63 kg per 100 kg input (for clean PE/PP feedstock) is the key revenue metric — this number is the commercial target to hit and track.
  • Syngas (18 kg) is consumed internally as furnace fuel — it reduces diesel cost but does not appear in the revenue calculation directly.
  • Pre-processing loss of 10 kg means the reactor processes 90 kg per 100 kg received — this 10% pre-processing loss is accounted for in feedstock cost calculations.
  • Actual mass balance for contaminated municipal waste typically shows 20–25 kg pre-processing loss and 50–55 kg oil yield — 25–30% lower revenue per tonne received.

Frequently asked questions

How do I use the mass balance to check if my plant is performing correctly?

Weigh the incoming plastic at the gate (100 kg basis). Weigh the pre-processing reject bin after sorting and washing. Weigh the oil collected in tanks at the end of the batch. Weigh the char. Cross-check against your expected mass balance. If oil yield is significantly below expected (e.g., 45 kg vs 63 kg), check: (1) feedstock moisture (too wet reduces yield), (2) condenser efficiency (fouled condensers lose oil to the gas stream), (3) feedstock contamination (PVC and PET reduce oil yield).

What should I track daily to monitor mass balance performance?

Daily tracking: (1) Tonnes of plastic received and weighed in; (2) Tonnes of sorting rejects; (3) Litres of oil produced (with density measurement for kg conversion); (4) Char weight (estimate from skip weight if not precise); (5) Diesel consumed (if not self-sustaining, diesel use indicates something is wrong with syngas production or condenser). Monthly trend on oil yield % is the key management metric.
Last updated: Jun 11, 2026 License
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